Stabilized High‐Membered and Phase‐Pure 2D All Inorganic Ruddlesden–Popper Halide Perovskites Nanocrystals as Photocatalysts for the CO<sub>2</sub> Reduction Reaction
Cheng‐Chieh Lin, Jia‐Ying Li, Nian‐Zu She, S.-H. Huang, Chih‐Ying Huang, I‐Ta Wang, Fu‐Li Tsai, Chuan‐Yu Wei, Ting‐Yi Lee, Di‐Yan Wang, Cheng‐Yen Wen, Shao‐Sian Li, Atsushi Yabushita, Chih‐Wei Luo, Chia‐Chun Chen, Chun‐Wei Chen
Abstract
Abstract In contrast to the 2D organic‐inorganic hybrid Ruddlesden–Popper halide perovskites (RPP), a new class of 2D all inorganic RPP (IRPP) has been recently proposed by substituting the organic spacers with an optimal inorganic alternative of cesium cations (Cs + ). Nevertheless, the synthesis of high‐membered 2D IRPPs ( n > 1) has been a very challenging task because the Cs + need to act as both spacers and A‐site cations simultaneously. This work presents the successful synthesis of stable phase‐pure high‐membered 2D IRPPs of Cs n+1 Pb n Br 3n+1 nanosheets (NSs) with n = 3 and 4 by employing the strategy of using additional strong binding bidentate ligands. The structures of the 2D IRPPs ( n = 3 and 4) NSs are confirmed by powder X‐ray diffraction and high‐resolution aberration‐corrected scanning transmission electron microscope measurements. These 2D IRPPs NSs exhibit a strong quantum confinement effect with tunable absorption and emission in the visible light range by varying their n values, attributed to their inherent 2D quantum‐well structure. The superior structural and optical stability of the phase‐pure high‐membered 2D IRPPs make them a promising candidate as photocatalysts in CO 2 reduction reactions with outstanding photocatalytic performance and long‐term stability.