Physical Delithiation of Epitaxial LiCoO<sub>2</sub> Battery Cathodes as a Platform for Surface Electronic Structure Investigation
Elena Salagre, P. Segovia, M.A. González, Matteo Jugovac, Paolo Moras, Igor Píš, Federica Bondino, J. C. Pearson, Richmond Wang, Ichiro Takeuchi, Elliot J. Fuller, Alec Talin, A. Mascaraque, E. G. Michel
Abstract
High Resolution Image Download MS PowerPoint Slide We report a novel delithiation process for epitaxial thin films of LiCoO 2 (001) cathodes using only physical methods, based on ion sputtering and annealing cycles. Preferential Li sputtering followed by annealing produces a surface layer with a Li molar fraction in the range 0.5 < x < 1, characterized by good crystalline quality. This delithiation procedure allows the unambiguous identification of the effects of Li extraction without chemical byproducts and experimental complications caused by electrolyte interaction with the LiCoO 2 surface. An analysis by X-ray photoelectron spectroscopy (XPS) and X-ray absorption spectroscopy (XAS) provides a detailed description of the delithiation process and the role of O and Co atoms in charge compensation. We observe the simultaneous formation of Co 4+ ions and of holes localized near O atoms upon Li removal, while the surface shows a (2 × 1) reconstruction. The delithiation method described here can be applied to other crystalline battery elements and provide information on their properties that is otherwise difficult to obtain.