Emerging applications for living crystallization-driven self-assembly
Liam R. MacFarlane, Chuanqi Zhao, Jiandong Cai, Huibin Qiu, Ian Manners
Abstract
20 nm to 10 μm). The method has been applied to a rapidly expanding range of crystallizable polymeric amphiphiles, which includes block copolymers and charge-capped homopolymers, to form assemblies with crystalline cores and solvated coronas. Living CDSA seeded growth methods have also been transposed to a wide variety of π-stacking and hydrogen-bonding molecular species that form supramolecular polymers in processes termed "living supramolecular polymerizations". In this article we outline the main features of the living CDSA method and then survey the promising emerging applications for the resulting nanoparticles in fields such as nanomedicine, colloid stabilization, catalysis, optoelectronics, information storage, and surface functionalization.