Opening the pathway towards a scalable electrochemical semi-hydrogenation of alkynols<i>via</i>earth-abundant metal chalcogenides
Kevinjeorjios Pellumbi, Leon Wickert, Julian T. Kleinhaus, Jonas Wolf, Allison Leonard, David Tetzlaff, Roman Goy, Jonathan Medlock, Kai junge Puring, Rui Cao, Daniel Siegmund, Ulf‐Peter Apfel
Abstract
, Faraday efficiencies of up to 75%, and an alkene selectivity of up to 90%. In this scalable setup we demonstrate high stability of catalyst and electrode for at least 100 h. Altogether, we illustrate the successful integration of a sustainable catalyst into a scalable zero-gap electrolyser establishing electrosynthetic methods in an application-oriented manner.
Topics & Concepts
ElectrochemistryMetalScalabilityEarth (classical element)ChemistryMaterials scienceCombinatorial chemistryOrganic chemistryElectrodeComputer scienceMathematicsPhysical chemistryDatabaseMathematical physicsElectrocatalysts for Energy ConversionAdvanced Photocatalysis TechniquesSulfur-Based Synthesis Techniques