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On the molecular architectures of siloxane coordination compounds: (re-)investigating the coordination of the cyclodimethylsiloxanes D<sub>n</sub>(<i>n</i>= 5–8) towards alkali metal ions

Fabian Dankert, Lukas Erlemeier, Christian Ritter, Carsten von Hänisch

2020Inorganic Chemistry Frontiers27 citationsDOI

Abstract

Cyclodimethylsiloxanes have been used as complex ligands and silyl-ether bonding towards various cations is explored stepwise. Compounds with unprecedented coordination modes as well as novel molecular architectures are obtained and characterized.

Topics & Concepts

Alkali metalSiloxaneCoordination complexSilylationEtherChemistryIonCoordination numberMetalMaterials scienceCrystallographyOrganic chemistryCatalysisPolymerSilicone and Siloxane ChemistryOrganometallic Compounds Synthesis and CharacterizationFluorine in Organic Chemistry
On the molecular architectures of siloxane coordination compounds: (re-)investigating the coordination of the cyclodimethylsiloxanes D<sub>n</sub>(<i>n</i>= 5–8) towards alkali metal ions | Litcius