Catalyst-free defluorinative alkylation of trifluoromethyls
Yan Huang, Yuan-Cui Wan, Yu Shao, Le‐Wu Zhan, Bindong Li, Jing Hou
Abstract
A visible-light induced catalyst-free strategy was developed for the defluorinative alkylation of trifluoromethyls via CO 2 ˙ − . Various of trifluoromethyl derivatives and alkenes could participate in the reaction smoothly.
Topics & Concepts
AlkylationCatalysisTrifluoromethylChemistryVisible spectrumOrganic chemistryCombinatorial chemistryPhotochemistryMaterials scienceAlkylOptoelectronicsFluorine in Organic ChemistryCarbon dioxide utilization in catalysisInorganic Fluorides and Related Compounds