CsPbBr<sub>3</sub> in the Activation of the C–Br Bond of CBrX<sub>3</sub> (X = Cl, Br) under Sunlight
Anupam Manna, Tarun Kumar Dinda, Subhadip Ghosh, Prasenjit Mal
Abstract
A newly synthesized green-fluorescent, orthorhombic, bromide-rich, perovskite nanocrystal (Φ ∼ 0.93, τ ∼ 12.5 ns, E ox = +1.6 V) obtained from an unprecedented bromide precursor dibromoisocyanuric acid was found to be an excellent visible-light (sunlight or blue-light-emitting diode (LED)) photocatalyst toward the synthesis of gem -dihaloenones for the first time. The photoactivated CsPbBr 3 catalyzed the homolytic cleavage of CBrX 3 (X = Cl, Br) to generate the • CX 3 radical, which underwent cascaded C–C cross-coupling with terminal alkynes into the corresponding gem -dihaloenones. Radical-trapping experiments and luminescence-quenching studies helped establish a single-electron-transfer (SET) mechanism. Interestingly, other highly stable CsPbBr 3 NCs, obtained from N -bromosuccinimide (NBS) and dibromohydantoin (DBHT) precursors, are unable to carry out these transformations. These results not only enrich the CsPbBr 3 synthetic methodology but also encourage the research community to develop efficient and cost-effective photocatalytic materials.