An optically reversible room-temperature solid-state cobalt(<scp>iii</scp>) photoswitch based on nitro-to-nitrito linkage isomerism
Krystyna A. Deresz, Radosław Kamiński, Sylwia E. Kutniewska, Adam Krówczyński, Dominik Schaniel, Katarzyna N. Jarzembska
Abstract
The first transition-metal nitro complex that exhibits optically reversible room-temperature photoswitchability with notable nitro-to-nitrito conversion of ca. 55% is reported.
Topics & Concepts
PhotoswitchNitroCobaltSolid-stateTransformation (genetics)ChemistryMaterials scienceCrystallographyPhotochemistryInorganic chemistryOrganic chemistryPhysical chemistryBiochemistryGeneAlkylPhotochromic and Fluorescence ChemistryPorphyrin and Phthalocyanine ChemistryMolecular Sensors and Ion Detection