Hybrid Catalysts for Enantioselective Photo-Phosphoric Acid Catalysis
Alessa B. Rolka, Nataliya Archipowa, Roger Jan Kutta, Burkhard König, F. Dean Toste
Abstract
The syntheses of two novel, organic, and chiral photocatalysts are presented. By combining donor-acceptor cyanoarene-based photocatalysts with a chiral phosphoric acid, bifunctional catalysts have been designed. In preliminary proof-of-concept reactions, their use in both enantioselective energy transfer and photoredox catalysis is demonstrated.
Topics & Concepts
Enantioselective synthesisPhosphoric acidBifunctionalCatalysisCombinatorial chemistryChemistryOrganocatalysisAcceptorOrganic chemistryMaterials sciencePhysicsCondensed matter physicsRadical Photochemical ReactionsSulfur-Based Synthesis TechniquesAdvanced Photocatalysis Techniques