Pd/Ni-Catalyzed Germa-Suzuki coupling <i>via</i> dual Ge–F bond activation
Hajime Kameo, Akihiro Mushiake, Tomohito Isasa, Hiroyuki Matsuzaka, Didier Bourissou
Abstract
Pd/Ni → Ge-F interactions supported by phosphine-chelation were found to trigger dual activation of Ge-F bonds under mild conditions. This makes fluoro germanes suitable partners for catalytic Ge-C cross-coupling and enables Germa-Suzuki reactions to be achieved for the first time.
Topics & Concepts
PhosphineDual (grammatical number)CatalysisChelationCoupling (piping)ChemistryCrystallographyMaterials scienceInorganic chemistryMetallurgyOrganic chemistryPhilosophyLinguisticsCatalytic Cross-Coupling ReactionsCatalytic C–H Functionalization MethodsCyclopropane Reaction Mechanisms