From AgTeO<sub>2</sub>F and Ag<sub>2</sub>(TeO<sub>2</sub>F<sub>2</sub>) to Ag<sub>3</sub>F<sub>3</sub>(TeF<sub>6</sub>)(TeO<sub>2</sub>)<sub>12</sub>: the first silver tellurite oxyfluorides with linear and nonlinear optical properties
Bo Zhang, Jia-Hang Wu, Chun‐Li Hu, Yafeng Li, Fang Kong, Jiang‐Gao Mao
Abstract
AgTeO 2 F and Ag 2 (TeO 2 F 2 ) are the first silver fluorotellurites, while Ag 3 F 3 (TeF 6 )(TeO 2 ) 12 is the first silver fluoride tellurite. Ag 3 F 3 (TeF 6 )(TeO 2 ) 12 features an NCS mixed valence Te oxyfluoride with an SHG intensity of about 70% that of commercial KDP.
Topics & Concepts
Valence (chemistry)CrystallographyMaterials scienceAnalytical Chemistry (journal)MineralogyChemistryOrganic chemistryChromatographyCrystal Structures and PropertiesInorganic Fluorides and Related CompoundsGlass properties and applications