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Enhancement of intersystem crossing in asymmetrically substituted BODIPY photosensitizers

Mikhail A. Filatov, Tatsiana Mikulchyk, Maxime Hodée, Metodej Dvoracek, VENKATA NANDA KISHORE N.K. MAMILLAPALLI, Aimee Sheehan, Craig Newman, Sergey M. Borisov, Daniel Escudero, Izabela Naydenova

2025Journal of Materials Chemistry C20 citationsDOIOpen Access PDF

Abstract

Asymmetrically substituted BODIPY photosensitizers achieve efficient intersystem crossing (ISC) through an S 1 → T 2 pathway, facilitated by a narrowed singlet–triplet energy gap.

Topics & Concepts

Intersystem crossingBODIPYPhotochemistryMaterials scienceFluorescenceExcited stateChemistryOpticsAtomic physicsPhysicsSinglet statePhotodynamic Therapy Research StudiesPorphyrin and Phthalocyanine ChemistryNanoplatforms for cancer theranostics