Selective adsorption of fluorinated super greenhouse gases within a metal–organic framework with dynamic corrugated ultramicropores
Bevan S. Whitehead, William W. Brennessel, Shane S. Michtavy, Hope A. Silva, Jaehwan Kim, Phillip J. Milner, Marc D. Porosoff, Brandon R. Barnett
Abstract
A hydrophobic metal–organic framework displays some of the largest selectivities known for adsorption of the fluorinated greenhouse gases CF 4 and CHF 3 over N 2 .
Topics & Concepts
AdsorptionGreenhouse gasMetalChemistryMetal-organic frameworkChemical engineeringInorganic chemistryOrganic chemistryEngineeringGeologyOceanographyMetal-Organic Frameworks: Synthesis and ApplicationsInorganic Fluorides and Related CompoundsMethane Hydrates and Related Phenomena