Controllable Synthesis of Skeletonized V<sub>2</sub>O<sub>5</sub> Microspheres Derived from a V-MOF for Aqueous Zinc-Ion Batteries
Ningning Yu, Man Li, Xiaowen Chen, Lei Xu, Wenyu Wang, Fuxiang Wei, Yanwei Sui, Qingqing Yan, Song Wang
Abstract
Low-cost, environmentally friendly aqueous zinc-ion batteries (ZIBs) exhibit tremendous potential in energy storage; however, the research of cathode materials that enable meeting the requirements of high capacity and cycling performance is still in the exploratory stage. This research synthesizes unique skeletonized V 2 O 5 microspheres by facile calcination using a spherical vanadium metal–organic framework (V-MOF) as the template. Owing to the three-dimensional porous structure, the V 2 O 5 cathode considerably enhances the kinetics of the ionic reaction. In addition, the prepared V 2 O 5 has a mixed valence state, which improves the electrochemical activity and reduces the polarization. As a result, its application as the cathode in aqueous ZIBs exhibits excellent electrochemical qualities. It reaches a remarkable specific capacity of 449 mA h g –1 at 0.5 A g –1, and the specific capacity remains at 200 mA h g –1 after 1400 cycles at 5 A g –1 . These excellent performances indicate that V 2 O 5 prepared as a cathode material for aqueous ZIBs shows significant prospects.