Tracking the Diffusion-Controlled Lithiation Reaction of LiMn<sub>2</sub>O<sub>4</sub> by In Situ TEM
Torben Erichsen, Björn Pfeiffer, Vladimir Roddatis, Cynthia A. Volkert
Abstract
Spinel lithium manganese oxide (LixMn2O4) is used as an active material in battery cathodes. It is a relatively inexpensive and environmentally friendly material but suffers from capacity fade during use. The capacity losses are generally attributed to the formation of the tetragonal phase (x > 1) due to overpotentials at the surfaces of the micrometer-sized particles that are used in commercial electrodes. In this study, we investigate the mechanisms of tetragonal phase formation by performing electrochemical lithiation (discharging) in situ in the transmission electron microscope (TEM) utilizing diffraction and high resolution imaging as well as spectroscopy. We observe a sharp interface between the cubic spinel (x = 1) and the tetragonal phase (x = 2) that moves under lithium diffusion control. The tetragonal phase forms as a complex nanotwinned microstructure, presumably to relieve the stresses due to expansion during lithiation. We propose that the twinned microstructure stabilizes the tetragonal phase, adding to capacity loss upon deep discharge.