Gradient area-selective deposition for seamless gap-filling in 3D nanostructures through surface chemical reactivity control
Chi Thang Nguyen, Eun-Hyoung Cho, Bonwook Gu, Sunghee Lee, Haesung Kim, Jeongwoo Park, Neung-Kyung Yu, Sangwoo Shin, Bonggeun Shong, Jeong Yub Lee, Han‐Bo‐Ram Lee
Abstract
Abstract The integration of bottom-up fabrication techniques and top-down methods can overcome current limits in nanofabrication. For such integration, we propose a gradient area-selective deposition using atomic layer deposition to overcome the inherent limitation of 3D nanofabrication and demonstrate the applicability of the proposed method toward large-scale production of materials. Cp(CH 3 ) 5 Ti(OMe) 3 is used as a molecular surface inhibitor to prevent the growth of TiO 2 film in the next atomic layer deposition process. Cp(CH 3 ) 5 Ti(OMe) 3 adsorption was controlled gradually in a 3D nanoscale hole to achieve gradient TiO 2 growth. This resulted in the formation of perfectly seamless TiO 2 films with a high-aspect-ratio hole structure. The experimental results were consistent with theoretical calculations based on density functional theory, Monte Carlo simulation, and the Johnson-Mehl-Avrami-Kolmogorov model. Since the gradient area-selective deposition TiO 2 film formation is based on the fundamentals of molecular chemical and physical behaviours, this approach can be applied to other material systems in atomic layer deposition.