Synthesis of distibiranes and azadistibiranes by cycloaddition reactions of distibenes with diazomethanes and azides
Hanns M. Weinert, Christoph Wölper, Stephan Schulz
Abstract
Azadistibiranes and distibiranes formed in cycloaddition reactions of distibene [L(Me 2 N)GaSb] 2 with RN 3 and Me 3 Si(H)CN 2 . The mechanism of the reactions with PhN 3 and Me 3 SiN 3 and the electronic nature of the products were studied by DFT calculations.
Topics & Concepts
CycloadditionChemistryComputational chemistryReaction mechanismMechanism (biology)Medicinal chemistryCatalysisOrganic chemistryPhysicsQuantum mechanicsSynthesis and characterization of novel inorganic/organometallic compoundsOrganometallic Complex Synthesis and CatalysisChemical Reactions and Mechanisms