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Toroidal <i>versus</i> centripetal arrangement of the magnetic moment in a Dy4 tetrahedron

Qianqian Yang, Liviu Ungur, Liviu F. Chibotaru, Jinkui Tang

2022Chemical Communications27 citationsDOI

Abstract

A μ 4 –O bridged Dy4 tetrahedron shows a diamagnetic ground state originating from the toroidal arrangement of the magnetic moment rather than the centripetal anisotropies, as revealed by ab initio calculations.

Topics & Concepts

Centripetal forceTetrahedronToroidMoment (physics)PhysicsMagnetic momentGeometryClassical mechanicsMathematicsCondensed matter physicsNuclear physicsPlasmaMagnetism in coordination complexesLanthanide and Transition Metal ComplexesOrganic and Molecular Conductors Research
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