Exergetic efficiency and CO2 intensity of hydrogen supply chain including underground storage
Boyukagha Baghirov, Denis Voskov, R. Farajzadeh
Abstract
• Exergetic efficiency of the electricity-to-H 2 -to-electricity conversion process ranges from7% to 25%. • Underground hydrogen storage process exhibits an exergetic efficiency between 72-92%.. • Fugitive CH 4 during H 2 production stage significantly increases the CO 2 equivalent intensity of blue H 2 option. • Blue CH 4 (CH 4 +CCS) shows higher exergetic efficiency and lower CO 2 intensity than blue H 2 for electricity generation. Hydrogen plays a crucial role in the transition to low-carbon energy systems, especially when integrated into energy storage applications. In this study, the concept of exergy-return on exergy-investment (ERoEI) is applied to investigate the exergetic efficiency (defined as the ratio of useful exergy output to invested exergy input) and CO 2 equivalent intensity of the hydrogen supply chain, with a specific focus on the underground hydrogen storage process. Our findings reveal that the overall exergetic efficiency of the electricity-to-hydrogen-to-electricity conversion process can reach up to 25 %. Among the hydrogen production methods, green hydrogen, produced via electrolysis powered by renewable energy, exhibits the lowest CO 2 equivalent intensity. Blue hydrogen, produced from natural gas with carbon capture, can significantly reduce the carbon footprint of electricity generation, though this advantage comes at the expense of decreased exergetic efficiency. Analysis further indicates that the exergetic efficiency of underground storage components ranges from 72 % to 92 %. A substantial fraction of the exergy is lost during compression and injection of the stored hydrogen. Nevertheless, the subsurface operations contribute a minimal CO 2 emission, between 1.46–4.56 grams of equivalent CO 2 per megajoule (gr-CO 2eq /MJ) when powered by low-carbon energy sources. Furthermore, it is found that hydrogen loss in the reservoir, along with methane and hydrogen leak during surface operations, notably affects the overall efficiency of the storage process.