DABSO as a SO<sub>2</sub> gas surrogate in the synthesis of organic structures
Mehri Seyed Hashtroudi, Vaezeh Fathi Vavsari, Saeed Balalaie
Abstract
the formation of a sulfinate radical or anion. Using DABSO as a reagent, various simple to complex structures can be constructed, such as metal sulfinates, sulfonyl fluorides, sulfonamides, sulfonohydrazides, sulfonic esters, sulfonic thioesters, and sulfones. In this review, we want to investigate mechanistically the role of DABSO in organic synthesis.
Topics & Concepts
ChemistryDABCOReagentAlkylOrganic synthesisSulfonylOrganic chemistryArylSulfur dioxideSulfurOctaneHalideSulfonic acidAnnulationCatalysisSulfur-Based Synthesis TechniquesRadical Photochemical ReactionsChemical Synthesis and Reactions