Facile Fabrication of a Robust Superhydrophilic/Underwater Superoleophobic Material for Oil-Fouling Expulsion
Tinghan Yang, Pan Wu, Changjun Liu, Zunzhao Li, Wei Wang, Yang Xu, Haibo Wang, Wei Jiang
Abstract
The reduction of oil fouling in pipes and tanks is essential for the oil storage and transportation industry. In this study, a superhydrophilic/underwater superoleophobic surface (SUSS) with high wearability, weatherability, and durability was developed using a facile two-step synthesis method and used to expel fouled oil from the surface using water without a surfactant. Some typical oils, including kerosene and white oil, can be spontaneously expelled by static water; however, rapeseed oil requires motive water for expulsion because of its high affinity for the SUSS. Different occurrences can be estimated based on a correlated parameter, φ( P e ), which is calculated using an introduced dimensionless number, P e = σ L V u μ . A positive value of φ indicates the occurrence of fouled-oil expulsion by water replacement, whereas a negative value indicates no occurrence of this phenomenon. This study provides a facile strategy for the rapid cleansing of oil-fouled pipes and tanks without using a detergent, thereby lowering costs and environmental risks.