π-Conjugated polymeric phthalocyanine for the oxidative coupling of amines
Haihong Wu, Yanwei Cao, Gangli Zhu, Dehong Zeng, Xiang Zhu, Jimin Du, Lin He
Abstract
A cross-linked π-conjugated polymeric cobalt phthalocyanine material was developed by a facile, economical, scalable, and solid-phase synthesis method. In addition to being highly recyclable, this material showed greatly enhanced activity for the aerobic oxidative coupling of amines compared with a molecular catalyst before heterogenization, indicating good prospects for the material with a π-conjugated electronic character.
Topics & Concepts
Conjugated systemPhthalocyanineOxidative phosphorylationChemistryOxidative coupling of methaneCobaltPhotochemistryPolymer chemistryOrganic chemistryPolymerCatalysisBiochemistryOxidative Organic Chemistry ReactionsCatalytic C–H Functionalization MethodsPorphyrin and Phthalocyanine Chemistry