Recent Advances in Carbonyl‐Photoredox/Transition Metal Dual Catalysis
Da‐Liang Zhu, Jie Li, David James Young, Yanqing Wang, Hong‐Xi Li
Abstract
Abstract Organic transformations using carbonyl‐photoredox/metal dual catalysis have attracted much attention in recent years. Abundant and inexpensive carbonyl photosensitizers effectively serve as single electron, energy or hydrogen atom transfer agents to induce metal‐catalyzed cross‐coupling and dicarbofunctionalization of olefins. This review covers literature reports of metal‐catalyzed photocatalytic coupling reactions from 2020 to mid‐2023, with a focus on C−C (C(sp 3 )−C(sp 3 ), C(sp 3 )−C(sp 2 ), C(sp 2 )−C(sp 2 ), C(sp 2 )−C(sp)) and C‐heteroatom (C(sp 3 )−S, C(sp 3 )−N, C(sp 2 )−O, C(sp 2 )−S, C(sp 2 )−P, C(sp 2 )−B) bond forming reactions.
Topics & Concepts
ChemistryCatalysisHeteroatomTransition metalPhotochemistryPhotocatalysisPhotoredox catalysisElectron transferMetalMetal carbonylHydrogen atomMedicinal chemistryStereochemistryCombinatorial chemistryOrganic chemistryRing (chemistry)AlkylRadical Photochemical ReactionsCatalytic C–H Functionalization MethodsSulfur-Based Synthesis Techniques