The impact of counterion on the metastable state properties of nitrosyl ruthenium complexes
Artem A. Mikhailov, Vladislav Yu. Komarov, A. S. Sukhikh, Denis P. Pishchur, Dominik Schaniel, Gennadiy А. Коstin
Abstract
Complexes of the <italic>trans</italic>-[RuNO(NH<sub>3</sub>)<sub>4</sub>F]<sup>2+</sup> cation with noble-metal anions [PtCl<sub>6</sub>]<sup>2−</sup>, [PdCl<sub>4</sub>]<sup>2−</sup>, and [PtCl<sub>4</sub>]<sup>2−</sup>, and perchlorate ClO<sub>4</sub><sup>−</sup> were synthesized, the photo-generated linkage isomers were studied by spectroscopic and calorimetric methods.
Topics & Concepts
ChemistryRutheniumCounterionLinkage isomerismMetastabilityPerchlorateGroup 2 organometallic chemistryCrystallographyMetalInorganic chemistryIonMoleculeBiochemistryCatalysisOrganic chemistryMetal complexes synthesis and propertiesMagnetism in coordination complexesMetal-Catalyzed Oxygenation Mechanisms