Stereoelectronic and dynamical effects dictate nitrogen inversion during valence isomerism in benzene imine
Nilangshu Mandal, Ankita Das, Chandralekha Hajra, Ayan Datta
Abstract
Non-classical processes such as heavy-atom tunneling and post transition-state dynamics govern stereoselectivity for benzene imine ⇌ 1 H -azepine.
Topics & Concepts
AzepineChemistryImineValence (chemistry)BenzeneNitrogen inversionIsomerizationStereochemistryNitrogenOrganic chemistryCatalysisAdvanced Chemical Physics StudiesChemical Reaction MechanismsChemical Reactions and Mechanisms