Aliphatic sulfonyl fluoride synthesis <i>via</i> reductive decarboxylative fluorosulfonylation of aliphatic carboxylic acid NHPI esters
Zhanhu Ma, Yongan Liu, Xiaoyu Ma, Xiaojun Hu, Yong Guo, Qing‐Yun Chen, Chao Liu
Abstract
A general and efficient approach to various aliphatic sulfonyl fluorides by the reductive decarboxylative fluorosulfonylation of aliphatic carboxylic acids via a radical sulfur dioxide insertion and fluorination strategy was developed.
Topics & Concepts
ChemistrySulfonylFluorideCarboxylic acidOrganic chemistrySulfurSulfur dioxideInorganic chemistryAlkylSulfur-Based Synthesis TechniquesChemical Synthesis and ReactionsRadical Photochemical Reactions