Valence Bond Theory—Its Birth, Struggles with Molecular Orbital Theory, Its Present State and Future Prospects
Sason Shaik, David Danovich, Philippe C. Hiberty
Abstract
This essay describes the successive births of valence bond (VB) theory during 1916-1931. The alternative molecular orbital (MO) theory was born in the late 1920s. The presence of two seemingly different descriptions of molecules by the two theories led to struggles between the main proponents, Linus Pauling and Robert Mulliken, and their supporters. Until the 1950s, VB theory was dominant, and then it was eclipsed by MO theory. The struggles will be discussed, as well as the new dawn of VB theory, and its future.
Topics & Concepts
Valence bond theoryModern valence bond theoryMolecular orbital theoryGeneralized valence bondValence (chemistry)BondMolecular orbitalTheoretical physicsPhysicsMoleculeQuantum mechanicsEconomicsFinanceHistory and advancements in chemistryVarious Chemistry Research TopicsChemical Thermodynamics and Molecular Structure