Highly Stereoselective Assembly of 1,2-<i>cis</i>-Ara<i>p</i> Linkages
Penghua Li, Hanyingzi Fan, Qiang Tan, Guozhi Xiao
Abstract
linkages has been achieved, which featured a broad range of alcoholic acceptors, including strong nucleophiles and complex bioactive molecules. This method was applied to a regioselective and orthogonal one-pot synthesis of a pentasaccharide, which was the structural motif of a side chain in type II arabinogalactan.
Topics & Concepts
StereoselectivityChemistryRegioselectivityNucleophileStereochemistryMoleculeCombinatorial chemistryOrganic chemistryCatalysisCarbohydrate Chemistry and SynthesisPolysaccharides and Plant Cell WallsGlycosylation and Glycoproteins Research