Divergent synthesis of nitrocyclopropanes and isoxazoline <i>N</i>-oxides from nitro compounds and vinyl sulfonium salts
Pavel Yu. Ushakov, Ivan S. Golovanov, Sema L. Ioffe, Andrey A. Tabolin
Abstract
A divergent approach toward polysubstituted nitro cyclopropanes and isoxazoline N -oxides is controlled by the choice of base and solvent.
Topics & Concepts
SulfoniumChemistryNitroSolventOrganic chemistryBase (topology)Divergent synthesisMedicinal chemistrySalt (chemistry)CatalysisMathematical analysisMathematicsAlkylCyclopropane Reaction MechanismsSynthesis and Catalytic ReactionsSynthesis and Biological Evaluation