<i>N</i>-Formylation of amines utilizing CO<sub>2</sub>by a heterogeneous metal–organic framework supported single-site cobalt catalyst
Rajashree Newar, Rahul Kalita, Naved Akhtar, Neha Antil, Manav Chauhan, Kuntal Manna
Abstract
Single-site cobalt-hydride supported on oxo-nodes of a porous aluminium metal–organic framework is a chemoselective and reusable catalyst for N -formylation of amines using CO 2 .
Topics & Concepts
FormylationCobaltCatalysisMetal-organic frameworkChemistryHydrideMetalAluminiumInorganic chemistryCombinatorial chemistryOrganic chemistryAdsorptionCarbon dioxide utilization in catalysisMetal-Organic Frameworks: Synthesis and ApplicationsAsymmetric Hydrogenation and Catalysis