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Oxidative control over the morphology of Cu<sub>3</sub>(HHTP)<sub>2</sub>, a 2D conductive metal–organic framework

Kathleen M. Snook, Leo B. Zasada, Dina Chehada, Dianne J. Xiao

2022Chemical Science55 citationsDOIOpen Access PDF

Abstract

The morphology of a copper-based 2D conductive metal–organic framework can be tuned via controlled ligand oxidation. Using quinone oxidants, we show how partial ligand oxidation prior to metal binding alters the nanocrystal aspect ratio by &gt;60-fold.

Topics & Concepts

Electrical conductorOxidative phosphorylationMorphology (biology)MetalNanotechnologyMaterials scienceControl (management)Chemical engineeringChemistryMetallurgyComputer scienceEngineeringComposite materialGeologyArtificial intelligenceBiochemistryPaleontologyMetal-Organic Frameworks: Synthesis and ApplicationsCovalent Organic Framework ApplicationsCopper-based nanomaterials and applications
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