Three isostructural MOFs based on different metal cations: proton conductivities and SC–SC transformation leading to magnetic changes
Huiqi Zou, Rong-Yun Li, Ding Li, Jing Lu, Haiquan Tian, Hui Yan, Hou‐Ting Liu, Suna Wang, Yunwu Li
Abstract
The different acidity of coordinated water molecule caused by different nature of metal cation leads to different proton conductivities of three isostructural MOFs. Additionally, obvious magnetic change based on SC–SC transformation was observed.
Topics & Concepts
IsostructuralProtonTransformation (genetics)MetalMoleculeChemistryInorganic chemistryCrystallographyMaterials scienceChemical physicsChemical engineeringCrystal structureOrganic chemistryPhysicsBiochemistryEngineeringGeneQuantum mechanicsMetal-Organic Frameworks: Synthesis and ApplicationsOrganic and Molecular Conductors ResearchSolid-state spectroscopy and crystallography