A general photo-induced wide-scope regioselective hydroboration of alkenes without using a photocatalyst or an external initiator
Yuqi Miao, Xinying Li, Qiao‐Jing Pan, Yubin Ma, Jiaxin Kang, Yan‐Na Ma, Zhenxing Liu, Xuenian Chen
Abstract
A general photo-induced regioselective hydroboration of alkenes without photocatalyst or an external initiator has been developed through in situ formed boryl radicals. Thiol plays the dual role as a proton donor and hydrogen atom transfer catalyst.
Topics & Concepts
HydroborationRegioselectivityChemistryPhotocatalysisRadicalCatalysisPhotochemistryHydrogen atomScope (computer science)Combinatorial chemistryOrganic chemistryGroup (periodic table)Computer scienceProgramming languageRadical Photochemical ReactionsSulfur-Based Synthesis TechniquesOrganoboron and organosilicon chemistry