Photoredox-catalyzed protecting-group-free<i>C</i>-glycosylation with glycosyl sulfinate<i>via</i>the Giese reaction
Taishi Miura, Makoto Yoritate, Go Hirai
Abstract
C -Glycoside analogs of naturally occurring glycoconjugates are useful tools for chemical biology studies, but their synthesis usually requires protection of the hydroxyl groups of the glycosyl donors.
Topics & Concepts
GlycosylationGlycosylChemistryGlycosyl donorCatalysisProtecting groupGroup (periodic table)StereochemistryOrganic chemistryBiochemistryAlkylSulfur-Based Synthesis TechniquesCarbohydrate Chemistry and SynthesisRadical Photochemical Reactions