Heteroleptic Lanthanide (La, Pr, Nd) Metal-Organic Frameworks Based on Chloranilic and Furandicarboxylic Acids
O. Yu. Trofimova, A. V. Maleeva, Kseniya V. Arsenyeva, A. V. Klimashevskaya, Anton V. Cherkasov, Alexandr V. Piskunov
Abstract
Abstract Novel heteroleptic lanthanum, praseodymium, and neodymium metal-organic coordination polymers (MOCPs) containing two types of anionic organic ligands as organic units are prepared by a two-step solvothermal synthesis in N,N-dimethylformamide. Framework derivatives with the [Ln2(CA)(fdc)2·4DMF]· ·2DMF composition are prepared (Ln = La, Pr, Nd; CA is a dianion of the chloranilic acid; fdc is a dianion of the 2,5-furandicarboxylic acid; DMF is N,N-dimethylformamide). The structure of the compounds is studied by XRD (CCDC CIF file No. 2251285 (I), 2251286 (II), 2251287 (III)).
Topics & Concepts
Chloranilic acidPraseodymiumLanthanideLanthanumChemistryMetalPolymer chemistryNeodymiumDimethylformamideMetal-organic frameworkInorganic chemistryMedicinal chemistryNuclear chemistryOrganic chemistryIonSolventAdsorptionLaserPhysicsOpticsMetal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesLanthanide and Transition Metal Complexes