A Preinstalled Protic Cation as a Switch for Superprotonic Conduction in a Metal–Organic Framework
Kazuya Otsubo, Shuya Nagayama, Shogo Kawaguchi, Kunihisa Sugimoto, Hiroshi Kitagawa
Abstract
times higher proton conductivity in comparison to that of the dehydrated form. Moreover, the anisotropy of single-crystal proton conductivity reveals the proton-conducting direction within the crystal. The present results offer insights into functional materials having a strong coupling of molecular dynamic motion and transport properties.
Topics & Concepts
ProtonMetal-organic frameworkConductivityChemistryThermal conductionProton conductorMetalChemical physicsMaterials sciencePhysical chemistryAdsorptionElectrolyteOrganic chemistryComposite materialPhysicsElectrodeQuantum mechanicsMetal-Organic Frameworks: Synthesis and ApplicationsOrganic and Molecular Conductors ResearchMachine Learning in Materials Science