Controlled Synthesis of Well-Defined Polyaminoboranes on Scale Using a Robust and Efficient Catalyst
Claire N. Brodie, Timothy M. Boyd, Lía Sotorríos, David E. Ryan, Eimear Magee, Steven Huband, James S. Town, Guy C. Lloyd‐Jones, David M. Haddleton, Stuart A. Macgregor, Andrew S. Weller
Abstract
) show a processing window that allows for melt extrusion of polyaminoborane strands, as well as hot pressing, drop casting, and electrospray deposition. By variation of conditions in the latter, smooth or porous microstructured films or spherical polyaminoboranes beads (∼100 nm) result.
Topics & Concepts
ChemistryCatalysisChain transferPolymerizationDehydrogenationPolymerNorbornadienePolymer chemistryOrganic chemistryRadical polymerizationOrganoboron and organosilicon chemistryOrganometallic Complex Synthesis and CatalysisCarbon dioxide utilization in catalysis