Mechanistic insights into the chemistry of compound I formation in heme peroxidases: quantum chemical investigations of cytochrome<i>c</i>peroxidase
Mohamed M. Aboelnga
Abstract
generated Ccp1 variants. Overall, we provide valuable findings toward solving the current ambiguity of the exact mechanism in Ccp1, which could be applied to peroxidases with similar heme pockets.
Topics & Concepts
PeroxidaseHemeChemistryCytochrome c peroxidaseQuantum chemicalMechanism (biology)HemeproteinStereochemistryComputational chemistryPhotochemistryBiochemistryEnzymeOrganic chemistryMoleculePhysicsQuantum mechanicsPhotosynthetic Processes and MechanismsHemoglobin structure and functionPorphyrin Metabolism and Disorders