Hierarchical Mg-Birnessite Nanowall Arrays with Enriched (010) Planes for High Performance Aqueous Mg-Ion Batteries
Zhengyi Shi, Liang Xue, Jianghua Wu, Qiubo Guo, Qiuying Xia, Mingzhu Ni, Peng Wang, Serguei V. Savilov, С. М. Алдошин, Feng Zan, Hui Xia
Abstract
Birnessite MnO 2 is a promising cathode material for aqueous Mg-ion batteries due to its layered structure with large interlayer distance. However, the two-dimensional growth mode of birnessite induces nanosheet morphology with preferred growth of inactive (001) planes with sluggish ion transport kinetics. In this work, a high Mg content birnessite with hierarchical nanowall arrays morphology is prepared by in situ electro-conversion using spinel Mn 3 O 4 nanowall arrays. The electro-conversion Mg-birnessite (ECMB) nanowall arrays are assembled by ultrasmall nanosheets with reduced (001) planes but increased active (010) planes, affording enriched open intercalation channels and shortened Mg 2+ diffusion length. Consequently, the ECMB cathode exhibits a large specific reversible capacity of about 255.1 mAh g −1 at a current density of 200 mA g −1 , and outstanding cycling stability with 73.6% capacity retention after 3000 cycles. Finally, a 2.2 V aqueous full cell is constructed by using ECMB as positive electrode and polyimide as negative electrode, which achieves a high energy density of 65.2 Wh kg −1 at a power density of 96 W kg −1 . This work demonstrates effective crystal plane modulation for Mg-birnessite to achieve superior Mg 2+ storage in aqueous batteries.