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Controlling the Iron Migration Mechanism for the Cretaceous Sediment Color Variations in Sichuan Basin, China

Haoyuan Jiang, Yanqing Xia, Jiyong Li, Shanpin Liu, Mingzhen Zhang, Yongchao Wang

2021ACS Omega10 citationsDOIOpen Access PDF

Abstract

index are 67.75, 79.94, 2.07, 0.26, and 0.26, respectively, indicating that chemical weathering is the most intense. The geochemical indexes corresponding to gray samples are 64.41, 74.91, 2.08, 0.19, and 0.24, respectively. Those corresponding to the gray-green samples are 62.30, 70.68, 2.17, 0.21, and 0.24, with the weakest chemical weathering. The ratio of Cu/Zn and the enrichment factor of V show that red and nonred bed samples are formed in weak oxidation and weak reduction environments, respectively. The red sample contains the highest content of hematite iron. The gray-green sample mainly represents paramagnetic ferrous in clay minerals. The geochemical contents of the gray sample's three iron elements are slightly different, mainly trivalent iron. The change in iron speciation content in different color samples shows that the Fe element forming hematite in red bed samples may come from the weathering of source rock and clay minerals subjected to secondary weathering. At present, it is confirmed that different colors of samples are related to different weathering degrees of source rocks, which can be related to hot, dry/humid climates. It is necessary to distinguish the climate type in combination with other indicators.

Topics & Concepts

HematiteWeatheringGeologyCretaceousRed bedsMineralogySedimentary rockGoethiteClay mineralsChemical compositionFerrousSedimentGeochemistryChemistryGeomorphologyPaleontologyOrganic chemistryAdsorptionGeochemistry and Elemental AnalysisGeological formations and processesPaleontology and Stratigraphy of Fossils
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