The large subunit of the regulatory [NiFe]-hydrogenase from<i>Ralstonia eutropha</i>– a minimal hydrogenase?
Giorgio Caserta, Christian Lorent, Alexandre Ciaccafava, Matthias Keck, Raffaella Breglia, Claudio Greco, Christian Limberg, Peter Hildebrandt, Stephen P. Cramer, Ingo Zebger, Oliver Lenz
Abstract
Spectroscopic investigation of an isolated [NiFe]-hydrogenase large subunit enables a unique view of the NiFe(CO)(CN)<sub>2</sub>cofactor.
Topics & Concepts
HydrogenaseRalstoniaProtein subunitCofactorChemistryBiochemistryEnzymeGeneMetalloenzymes and iron-sulfur proteinsElectrocatalysts for Energy ConversionHydrogen Storage and Materials