Surface stabilisation of the high-spin state of Fe(<scp>ii</scp>) spin-crossover complexes
Alejandro Martínez Serra, Archit Dhingra, M. C. Asensio, José Antonio Real, Juan F. Sánchez‐Royo
Abstract
temperature plots reveal that the surface of each of the molecules studied herein is found to be in the high-spin state at temperatures both in the vicinity of room temperature and below their respective transition temperature alike, with the stability of the high-spin state of these molecules varying with the choice of ligand.
Topics & Concepts
Spin crossoverSpin (aerodynamics)Spin statesX-ray photoelectron spectroscopyCondensed matter physicsMaterials scienceState (computer science)ChemistryCrystallographyPhysicsNuclear magnetic resonanceThermodynamicsMathematicsAlgorithmMagnetism in coordination complexesLanthanide and Transition Metal ComplexesMetal-Catalyzed Oxygenation Mechanisms