Photoinduced catalyst-free difluoromethylation–cyclization of indole derivatives <i>via</i> electron donor–acceptor complexes under visible light
Hong-Xian Jin, Yuping Zhu, Jie Zhang, Yunpeng Zhang, Ling Zhu, Lipeng Long, Zhengwang Chen, Haiqing Luo, Daohong Yu
Abstract
A novel catalyst-free photoinduced difluoromethylation–cyclization via electron donor–acceptor (EDA) complexes was developed for the synthesis of fluorinated compounds.
Topics & Concepts
ChemistryIndole testCatalysisAcceptorCombinatorial chemistryElectron acceptorPhotochemistryElectron donorVisible spectrumStereochemistryOrganic chemistryOptoelectronicsPhysicsCondensed matter physicsFluorine in Organic ChemistryRadical Photochemical ReactionsCatalytic C–H Functionalization Methods