A Cyaphide Transfer Reagent
Daniel W. N. Wilson, Stephanie J. Urwin, Eric S. Yang, José M. Goicoechea
Abstract
SiOCP with a magnesium(I) reagent. By analogy with Grignard reagents, these compounds can be used for the incorporation of the cyaphide ion into the coordination sphere of metals using a simple salt-metathesis protocol.
Topics & Concepts
ChemistryReagentCyanideCoordination complexSalt (chemistry)MagnesiumInorganic chemistryMetalCombinatorial chemistryMetathesisCoordination sphereOrganic chemistryPolymerizationPolymerSynthesis and characterization of novel inorganic/organometallic compoundsInorganic Chemistry and MaterialsOrganometallic Complex Synthesis and Catalysis