Layered Metal Chalcogenide ZnIn<sub>2</sub>S<sub>4</sub> Anchored with Nickel Metal Dots for Efficient Photocatalytic Production of Hydrogen Peroxide and Degradation of Sulfamethoxazole
He Gan, Qiong-Yu Wang, Zaixiang Xu, Wenhao Xing, Wei Chen, Zhangliang Han, Zhong-Ting Hu, Jianguo Wang
Abstract
Photocatalytic oxygen reduction reaction (ORR) through a two-electron pathway is a green, sustainable route for hydrogen peroxide (H 2 O 2 ) production. An outstanding visible-light-driven photocatalyst ZnIn 2 S 4 (ZIS) with anchoring nickel metal dots (Ni 0 ) less than one nanometer, namely, Ni/ZIS, has been successfully synthesized for H 2 O 2 production followed by effective degradation of sulfamethoxazole (SMX). As compared with the pristine, the Ni/ZIS H 2 O 2 production capacity exhibit 5 times the H 2 O 2 yield of >40.9 μmol/L in the presence of visible light illumination (λ = 420–630 nm). The light absorption capacity, photogenerated electron transfer rate, and lower recombination rate of photoelectron/hole pairs were improved through Ni metal dots, which was demonstrated in this study. Under the condition of visible light irradiation for 1 h, 1.5 mg/L SMX by 10 mg 1.0 wt % % Ni/ZIS was degraded over 93%. This study presents a facile strategy for enhancing photocatalysis of metal chalcogenide on H 2 O 2 production in the visible-light wavelength. It has potential for water purification by consuming on-site H 2 O 2 production under solar illumination.