Iridium-catalyzed arylation of sulfoxonium ylides and arylboronic acids: a straightforward preparation of α-aryl ketones
Bing Shu, Xiaotong Wang, Zi-Xuan Shen, Tong Che, Mei Zhong, Jia‐Lin Song, Hua‐Jie Kang, Hui Xie, Luyong Zhang, Shang‐Shi Zhang
Abstract
A highly efficient iridium(<sc>iii</sc>)-catalyzed arylation coupling of sulfoxonium ylides with arylboronic acids to generate α-aryl ketones has been established for the first time.
Topics & Concepts
ChemistryArylIridiumCatalysisCombinatorial chemistryOrganic chemistryAlkylCatalytic C–H Functionalization MethodsCatalytic Cross-Coupling ReactionsSulfur-Based Synthesis Techniques