An EPR study on the radiolysis of isolated ethanol molecules in solid argon and xenon: matrix control of radiation-induced generation of radicals in cryogenic media
Pavel V. Zasimov, Elizaveta V. Sanochkina, Daniil A. Tyurin, Vladimir I. Feldman
Abstract
The electron paramagnetic resonance (EPR) studies of radicals produced by irradiation of isolated ethanol molecules in solid Ar and Xe matrices at 7 K reveal the remarkable matrix effect on primary processes.
Topics & Concepts
Electron paramagnetic resonanceRadiolysisRadicalMatrix isolationMoleculeChemistryXenonEthanolMatrix (chemical analysis)IrradiationPhotochemistryArgonRadiochemistryNuclear magnetic resonanceOrganic chemistryNuclear physicsPhysicsChromatographyAtmospheric Ozone and ClimateMolecular Spectroscopy and StructureInorganic Fluorides and Related Compounds