The effect of fluorine substituents on the crystal structure and spin crossover behavior of the cation [Mn<sup>III</sup>(3,5-diHal-sal<sub>2</sub>323)]<sup>+</sup> complex family with BPh<sub>4</sub> anions
Aleksandra V. Tiunova, Anna V. Kazakova, Денис В. Корчагин, G.V. Shilov, Konstantin V. Zakharov, A. N. Vasiliev, Eduard B. Yagubskii
Abstract
The effect of fluorine substituents on the structure and magnetic behavior of [Mn( R ′, R ′′-sal 2 323)]BPh 4 complexes was studied and compared it with that of chlorine and bromine substituents.
Topics & Concepts
ChemistryFluorineBromineChlorineCrystal structureSpin crossoverCrystallographyInorganic chemistryOrganic chemistryMagnetism in coordination complexesLanthanide and Transition Metal ComplexesElectron Spin Resonance Studies