Carbon-Supported Noble-Metal Nanoparticles for Catalytic Applications—A Review
Agnieszka Karczmarska, Michał Adamek, Sara El Houbbadi, Paweł Kowalczyk, Magdalena Laskowska
Abstract
Noble-metal nanoparticles (NMNPs), with their outstanding properties, have been arousing the interest of scientists for centuries. Although our knowledge of them is much more significant today, and we can obtain NMNPs in various sizes, shapes, and compositions, our interest in them has not waned. When talking about noble metals, gold, silver, and platinum come to mind first. Still, we cannot forget about elements belonging to the so-called platinum group, such as ruthenium, rhodium, palladium, osmium, and iridium, whose physical and chemical properties are very similar to those of platinum. It makes them highly demanded and widely used in various applications. This review presents current knowledge on the preparation of all noble metals in the form of nanoparticles and their assembling with carbon supports. We focused on the catalytic applications of these materials in the fuel-cell field. Furthermore, the influence of supporting materials on the electrocatalytic activity, stability, and selectivity of noble-metal-based catalysts is discussed.