Novel energetic aminofurazans with a nitro-NNO-azoxy group
Nikita E. Leonov, Sergei E. Semenov, Michael S. Klenov, Aleksandr M. Churakov, Yurii A. Strelenko, Алла Н. Пивкина, Ivan V. Fedyanin, Д. Б. Лемперт, Т. С. Конькова, Yurii N. Matyushin, Evgeny A. Miroshnichenko, Vladimir A. Tartakovsky
Abstract
Novel energetic azoxy- and azofurazans bearing nitro-NNO- azoxy and amino groups were synthesized using the ammonolysis of some known (nitro-NNO-azoxy)furazans. 3-Amino-4-{[4′-(nitro-NNO-azoxy)f urazan-3′-yl]-NNO- azoxy}furazan displays the highest melting point (114 °C, decomp.) among the known (nitro-NNO-azoxy)furazans, optimal density (1.80 g cm−3), high experimental enthalpy of formation (639 kcal kg−1) and mechanical sensitivity on the level of PETN. In terms of the specific impulse level, the model solid composite propellant formulations based on this compound outperform similar formulations based on RDX, HMX or CL-20 by 7–12 s.